Synthesis of (-)-hamigeran B.
نویسندگان
چکیده
The synthesis of (-)-hamigeran B has been achieved, based on a new approach to cyclopentane construction, the rhodium-mediated intramolecular C-H insertion of alpha-aryl-alpha-diazoketones. The endo-isopropyl group was installed by selective hydrogenation of a cyclopropylidene substituent.
منابع مشابه
A catalytic, asymmetric formal synthesis of (+)-hamigeran B.
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 73 19 شماره
صفحات -
تاریخ انتشار 2008